Exploring the Density, Viscosity and Physico-chemical Characteristics of Dextran in Aqueous Glycine: An Ultrasonic Analysis
Keywords:
Dextran, Glycine, ultrasonic speed, density, viscosity, acoustical parametersAbstract
At 30 0C, 35 0C, 40 0C, 45 0C, and 50 0C, the density (ρ), viscosity (η), and ultrasonic speed (U) of the systems of dextran with glycine in the aqueous medium have been measured. Ultrasonic interferometers have been used to measure the ultrasonic speed at four distinct frequencies: 1, 5, 9, and 12MHz.The acoustic parameters free volume, internal pressure, absorption coefficient, Rao's constant, and Wada's constant are calculated using the measured parameters density (ρ), viscosity (η), and ultrasonic speed (U). The examination of molecular mobility, distinct types of intermolecular interactions, and the strength of the connection between the solute (dextran 0.5%) and solvent (glycine 2(M)) are all influenced by the variation of these parameters with temperature and frequency. The findings have been explained in terms of a structural reorganisation that takes place in the aqueous dextran solution. At all the temperatures used for the investigation, the solute-solvent interactions are greater. The change in the acoustic properties is small because the frequency variation causes the molecules to move swiftly and have little chance to interact. This analysis provides a lot of information regarding the physical and chemical behaviour of liquid solutions.
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